The role of discrete sample injection in trace mercury analysis by atomic fluorescence spectrometry

نویسندگان

  • P. B. Stockwell
  • W. T. Corns
  • N. Brahma
چکیده

Coupling specific atomic fluorescence spectrometers to vapour generation techniques is a highly sensitive approach to the determination of trace levels of mercury. In many sample types the levels of the mercury content are extremely high and the matrix may have a deleterious e2ffect on the measurement. This paper discusses the application of discrete sample injection techniques to broaden the range of analytes tested and the levels analysed. The limitation of linear dynamic range for fluorescence is the self-absorption e/ffect. Reducing the eective sample size to below 100 # litres allows a linear calibration up to 10 parts per million (ppm). This sample limitation, coupled to the software's ability to reset the sampling valve should the signal level exceed the maximum setting, ensures that levels of up to lOOppm can be presented to the analyser. An additional advantage of the discrete sample injection applies to complex analytical samples, for example concentrated sulphuric acid. The eective dilution provided by this means overcomes any matrix interferences and quickly provides correct data. With proper care, the analytical range of the system described can extend over seven orders of magnitude from less than 1 part per trillion (ppt) through to 10 ppm.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

استفاده از نانو ذرات نقره برای نمونه برداری از بخارات سمی جیوه از هوای محیط های صنعتی

Introduction: Mercury is one of the toxic metals that damages the nervous system and kidneys. Therefore, monitoring of mercury vapors in the environments is essential. .Material and Method: A new adsorbent was made from silver nanoparticles on a bed of quartz. The nano-adsorbent was capable for sampling of the trace amounts of mercury vapor from air. In this study, the required mercury vapor ...

متن کامل

Elimination of Chemical and Spectral Interferences in Measurement of Trace Elements in Urine and Blood by Combined Electrodeposition-Electrothermal Atomic Absorption Spectrometry

A combined electrodeposition-ETAAS technique has been applied to the analysis of Pb, Cd, Co, Ni, Cr and Mn in biological samples in order to overcome interferences and to minimize sample pretreatment. It requires minimal sample preparation with the electrolysis process aiding partial decomposition of the organic matrix, adequate for the release and deposition of trace elements. In an initia...

متن کامل

Determining Total Mercury in Samples from the Persian Gulf and theCaspian Sea: Comparison of Dry Ash and Wet Extraction Mothods

Monitoring of mercury in environmental samples, with its proven toxicity on the food chain, requires sensitive and accurate analytical techniques. In this study, two methods for identification and quantification of total mercury in biological and sediment samples are compared: i) dry ash preparation and subsequent established procedures for Combustion Atomic Absorption Spectrometry, (AMA 254) ...

متن کامل

Determination of mercury concentration in the air of dental clinics and the urines of their personnel with cold vapor atomic absorption spectrometry

Background: Dental clinics are known to be one of the largest users of Toxic inorganic mercury. It is well documented that dentists and dental assistants who work with amalgam are chronically exposed to mercury vapor. This study investigates exposure to mercury vapor in a dental clinic. Methods: GBC cold vapor atomic absorption spectrometry (AAS), using sodium borohydride as the reducing age...

متن کامل

Dispersive liquid–liquid microextraction based on solidification of floating organic drop combined with flame atomic absorption spectrometry for determination trace amount of cobalt in water samples

An efficient, rapid, simple, and highly selective dispersive liquid–liquid microextraction basedon solidification of floating organic drop (DLLME-SFOD), combined with flame atomicabsorption spectrometry was developed for preconcentration and determination of trace amountsof cobalt in water samples. In this method, an appropriate mixture of acetone and1-undecanol was injected rapidly into the aq...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • The Journal of Automatic Chemistry

دوره 18  شماره 

صفحات  -

تاریخ انتشار 1996